Kinetic and Size Control of Polystyrene and Polyacrylic Octadecyl Ester Lattices Via Polymerization in O/W Microemulsions

doi:10.1016/S0927-7757(01)00875-5

IMECH-IR > 力学所知识产出(1956-2008)

	Kinetic and Size Control of Polystyrene and Polyacrylic Octadecyl Ester Lattices Via Polymerization in O/W Microemulsions
	Zheng LQ(郑利强); Zhu WZ; Shen Q; Shui LL; Li GZ; Sun ZW(孙祉伟)
发表期刊	Colloids and Surfaces A: Physicochemical and Engineering Aspects
	2002
卷号	201 期号:13 页码:111-121
ISSN	0927-7757
摘要	The kinetic studies of the acrylic octadecyl ester and styrene polymerization in microemulsion systems, (1) cetyl pyridine bromide (CPDB)/t-butanol/styrene/water; (2) CPDB/t-butanol/toluene + acrylic octadecyl ester (1:1, w/v)/ water; (3) cetyl pyridine bromide/styrene/formamide, were made by using dynamic laser light scattering techniques (DLS). The mechanisms of nucleation of latex particles were discussed. The most possible nucleation location of the styrene and acrylic octadecyl ester microlatex particles in aqueous microemulsion system is in aqueous phase via homogeneous nucleation. Meanwhile, parts of microlatex particles are possibly produced via swollen micelles (microemulsions) and monomer droplets nucleation. On the other hand, the most possible nucleation location of the styrene microlatex particles in nonaqueous microemulsion system is inside monomer droplets. The relationship between the amount of monomer and the size of microlatex was also investigated. It has been found that the size of microlatex particles could be controlled by changing the amount of monomer. (C) 2002 Elsevier Science B.V. All rights reserved.
学科领域	力学
DOI	10.1016/S0927-7757(01)00875-5
收录类别	SCI
语种	英语
WOS记录号	WOS:000174783800011
WOS研究方向	Chemistry ; Polymer Science
WOS类目	Chemistry, Physical
引用统计	被引频次：4[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://dspace.imech.ac.cn/handle/311007/16035
专题	力学所知识产出(1956-2008)
推荐引用方式 GB/T 7714	Zheng LQ,Zhu WZ,Shen Q,et al. Kinetic and Size Control of Polystyrene and Polyacrylic Octadecyl Ester Lattices Via Polymerization in O/W Microemulsions[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects,2002,201,13,:111-121.
APA	郑利强,Zhu WZ,Shen Q,Shui LL,Li GZ,&孙祉伟.(2002).Kinetic and Size Control of Polystyrene and Polyacrylic Octadecyl Ester Lattices Via Polymerization in O/W Microemulsions.Colloids and Surfaces A: Physicochemical and Engineering Aspects,201(13),111-121.
MLA	郑利强,et al."Kinetic and Size Control of Polystyrene and Polyacrylic Octadecyl Ester Lattices Via Polymerization in O/W Microemulsions".Colloids and Surfaces A: Physicochemical and Engineering Aspects 201.13(2002):111-121.

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