IMECH-IR  > 等离子体与燃烧中心(2009-2011)
Behavior of Alkali Metal Hydroxides/Chlorides for NO Reduction in a Biomass Reburning Process
Li S(李森); Wei XL(魏小林); Li, S, Chinese Acad Sci, Inst Mech, 15 Beisihuanxi Rd, Beijing 100190, Peoples R China
Source PublicationEnergy & Fuels
2011
Volume25Issue:8Pages:3465-3475
ISSN0887-0624
AbstractThe behaviors of alkali metal hydroxides and chlorides released from biomass for NO reduction during biomass rebuming were analyzed. Na-Containing species have great promotion of NO reduction by controlling the free radicals of H and OH, as compared to K-containing species, and the effects of alkali metal hydroxide vapors and alkali metal chloride vapors on the NO reduction rate were identical. At the beginning stage of biomass rebuming, Na-containing species can effectively inhibit the conversion of HCN into NH, HNO, and N by controlling the formation of H and OH, and it avoids NO formation. At the later stage of biomass reburning, the free-radical levels of H and OH reach equilibrium, Na-containing species can promote the formation of H and OH to sustain a relatively high level through the chemical reaction path of NaOH -> Na -> NaOH, and NO is effectively reduced. Because the reaction rate constant of K + OH = KOH is only (1)/64 of Na + OH = NaOH, KOH has low promotion of NO reduction, as compared to NaOH.
KeywordCombustion So2 Optimization Oxidation Additives Furnace Hcl Jsr
Subject AreaEnergy & Fuels ; Engineering
DOI10.1021/ef200661x
URL查看原文
Indexed BySCI ; EI
Language英语
WOS IDWOS:000294077100012
WOS KeywordCOMBUSTION ; SO2 ; OPTIMIZATION ; OXIDATION ; ADDITIVES ; FURNACE ; HCL ; JSR
WOS Research AreaEnergy & Fuels ; Engineering
WOS SubjectEnergy & Fuels ; Engineering, Chemical
Funding OrganizationFinancial support by the National Natural Science Foundation of China (50976123 and 50776099) and the Knowledge Innovation Program of the Chinese Academy of Sciences (KGCX2-YW-321) is acknowledged.
DepartmentLHD高效洁净燃烧(CPCR)
Classification二类/Q1
Citation statistics
Document Type期刊论文
Identifierhttp://dspace.imech.ac.cn/handle/311007/44861
Collection等离子体与燃烧中心(2009-2011)
Corresponding AuthorLi, S, Chinese Acad Sci, Inst Mech, 15 Beisihuanxi Rd, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Li S,Wei XL,Li, S, Chinese Acad Sci, Inst Mech, 15 Beisihuanxi Rd, Beijing 100190, Peoples R China. Behavior of Alkali Metal Hydroxides/Chlorides for NO Reduction in a Biomass Reburning Process[J]. Energy & Fuels,2011,25(8):3465-3475.
APA 李森,魏小林,&Li, S, Chinese Acad Sci, Inst Mech, 15 Beisihuanxi Rd, Beijing 100190, Peoples R China.(2011).Behavior of Alkali Metal Hydroxides/Chlorides for NO Reduction in a Biomass Reburning Process.Energy & Fuels,25(8),3465-3475.
MLA 李森,et al."Behavior of Alkali Metal Hydroxides/Chlorides for NO Reduction in a Biomass Reburning Process".Energy & Fuels 25.8(2011):3465-3475.
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