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Imaging the homogeneous nucleation during the melting of superheated colloidal crystals
Wang ZR; Wang F; Peng Y; Zheng ZY(郑中玉); Han YL; Han, YL; Hong Kong Univ Sci & Technol, Dept Phys, Hong Kong, Hong Kong, Peoples R China.
发表期刊SCIENCE
2012-10-05
卷号338期号:6103页码:87-90
ISSN0036-8075
摘要The nucleation process is crucial to many phase transitions, but its kinetics are difficult to predict and measure. We superheated and melted the interior of thermal-sensitive colloidal crystals and investigated by means of video microscopy the homogeneous melting at single-particle resolution. The observed nucleation precursor was local particle-exchange loops surrounded by particles with large displacement amplitudes rather than any defects. The critical size, incubation time, and shape and size evolutions of the nucleus were measured. They deviate from the classical nucleation theory under strong superheating, mainly because of the coalescence of nuclei. The superheat limit agrees with the measured Born and Lindemann instabilities.
关键词Phase-transition Stability Limit Catastrophe Science Growth Bulk
学科领域流体力学
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收录类别SCI
语种英语
WOS记录号WOS:000309457400058
项目资助者This work was supported by the Research Grants Council of Hong Kong (General Research Fund 601208 and 601911), and we thank A. Alsayed and A. Yodh for providing the NIPA colloids.
课题组名称NML空间材料物理力学
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被引频次:141[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://dspace.imech.ac.cn/handle/311007/46586
专题微重力重点实验室
通讯作者Han, YL; Hong Kong Univ Sci & Technol, Dept Phys, Hong Kong, Hong Kong, Peoples R China.
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Wang ZR,Wang F,Peng Y,et al. Imaging the homogeneous nucleation during the melting of superheated colloidal crystals[J]. SCIENCE,2012,338,6103,:87-90.
APA Wang ZR.,Wang F.,Peng Y.,Zheng ZY.,Han YL.,...&Hong Kong Univ Sci & Technol, Dept Phys, Hong Kong, Hong Kong, Peoples R China..(2012).Imaging the homogeneous nucleation during the melting of superheated colloidal crystals.SCIENCE,338(6103),87-90.
MLA Wang ZR,et al."Imaging the homogeneous nucleation during the melting of superheated colloidal crystals".SCIENCE 338.6103(2012):87-90.
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