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Using Electrochemistry - Total Internal Reflection Ellipsometry Technique to Observe the Dissolved Oxygen Reduction on Clark Electrode
Liu W; Li M; Luo ZR(罗子人); Jin G(靳刚); Jin, G (reprint author), Chinese Acad Sci, Inst Mech, NML, 15 Bei Si Huan West Rd, Beijing 100190, Peoples R China.
Source PublicationELECTROCHIMICA ACTA
2014-10-01
Volume142Pages:371-377
ISSN0013-4686
AbstractThe high interface sensitivity in the ellipsometric phase shift, Delta, makes total internal reflection ellipsometry (TIRE) a useful tool to study redox reactions on the electrode surface. Electrochemistry - total internal reflection ellipsometry (EC-TIRE) is proposed to observe the refractive index change induced by the reduction of the dissolved oxygen (DO) on Clark electrode. In order to analyze the TIRE signal change caused by the reaction, we have calculated the refractive index variation on the surface of Clark electrode. We have found that the calculation under the thin layer boundary condition is more persuasive than that under the semi-infinite boundary condition not only in the steady state measurement but in the dynamic process. (C) 2014 Elsevier Ltd. All rights reserved.
KeywordTotal Internal Reflection Ellipsometry Clark Electrode Evanescent Wave Electrochemistry Dissolved Oxygen Detection
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Indexed BySCI
Language英语
WOS IDWOS:000343626400046
Funding OrganizationThe authors acknowledge the financial support to the National Natupral Science Foundation of China (21305147), to the International Science & Technology Cooperation Program of China (2012DFG31880), to the National Basic Research Program of China (2009CB320302), to the National High Technology Research Development Program of China (2008AA02Z419), and to the Instrument Developing Project of the Chinese Academy of Sciences (KJCX2-YW-M04, KJCX2-YW-M03).
DepartmentNML纳米生物光学
Classification一类
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Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://dspace.imech.ac.cn/handle/311007/49339
Collection国家微重力实验室
Corresponding AuthorJin, G (reprint author), Chinese Acad Sci, Inst Mech, NML, 15 Bei Si Huan West Rd, Beijing 100190, Peoples R China.
Recommended Citation
GB/T 7714
Liu W,Li M,Luo ZR,et al. Using Electrochemistry - Total Internal Reflection Ellipsometry Technique to Observe the Dissolved Oxygen Reduction on Clark Electrode[J]. ELECTROCHIMICA ACTA,2014,142:371-377.
APA Liu W,Li M,Luo ZR,Jin G,&Jin, G .(2014).Using Electrochemistry - Total Internal Reflection Ellipsometry Technique to Observe the Dissolved Oxygen Reduction on Clark Electrode.ELECTROCHIMICA ACTA,142,371-377.
MLA Liu W,et al."Using Electrochemistry - Total Internal Reflection Ellipsometry Technique to Observe the Dissolved Oxygen Reduction on Clark Electrode".ELECTROCHIMICA ACTA 142(2014):371-377.
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