Mechanical behavior and properties of hydrogen bonded graphene/polymer nano-interfaces | |
Dai ZH; Wang GR; Liu LQ; Hou Y; Wei YG(魏悦广); Zhang Z; Wei, YG (reprint author), Chinese Acad Sci, Inst Mech, State Key Lab Nonlinear Mech, Beijing 100190, Peoples R China.; Liu, LQ; Zhang, Z (reprint author), Natl Ctr Nanosci & Technol, CAS Ctr Excellence Nanosci, CAS Key Lab Nanosyst & Hierach Fabricat, Beijing 100190, Peoples R China. | |
发表期刊 | COMPOSITES SCIENCE AND TECHNOLOGY |
2016 | |
卷号 | 136页码:1-9 |
ISSN | 0266-3538 |
摘要 | There is increasing evidence in literature for significant improvements in both toughness and strength of graphene-based nanocomposites through engineering their nano-interfaces with hydrogen bonds (H-bonds). However, the underlying mechanical behaviors and properties of these H-bonded interfaces at the microscopic level were still not experimentally clarified and evaluated. Herein, this work reports a study on the interfacial stress transfer between a monolayer graphene and a commonly used poly(-methyl methacrylate) (PMMA) matrix under pristine vdW and modified H-bonding interactions. A nonlinear shear-lag model considering friction beyond linear bonding was proposed to understand evolution of interfacial stresses and further identify key interfacial parameters (such as interfacial stiffness, strength, frictional stress and adhesion energy) with the aid of in situ Raman spectroscopy and atomic force microscopy. The present study can provide fundamental insight into the reinforcing mechanism and unique mechanical behavior of chemically modified graphene nano-interfaces and develop further a basis for interfacial optimal design of graphene-based high-performance nanocomposites. (C) 2016 Published by Elsevier Ltd. |
关键词 | Interface Nano Composites Raman Spectroscopy Modelling Interfacial Strength |
DOI | 10.1016/j.compscitech.2016.09.005 |
URL | 查看原文 |
收录类别 | SCI ; EI |
语种 | 英语 |
WOS记录号 | WOS:000388775800001 |
关键词[WOS] | Interface ; Nano composites ; Raman spectroscopy ; Modelling ; Interfacial strength |
WOS研究方向 | Materials Science |
WOS类目 | Materials Science, Composites |
项目资助者 | National Key Basic Research Program of China [2012CB937503, 2013CB934203] ; National Natural Science Foundation of China [51173030, 11225210, 21474023, 11222217, 11225421, 11434010, 11474277] |
课题组名称 | LNM新型材料及结构的多尺度力学 |
论文分区 | 一类 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://dspace.imech.ac.cn/handle/311007/59945 |
专题 | 非线性力学国家重点实验室 |
通讯作者 | Wei, YG (reprint author), Chinese Acad Sci, Inst Mech, State Key Lab Nonlinear Mech, Beijing 100190, Peoples R China.; Liu, LQ; Zhang, Z (reprint author), Natl Ctr Nanosci & Technol, CAS Ctr Excellence Nanosci, CAS Key Lab Nanosyst & Hierach Fabricat, Beijing 100190, Peoples R China. |
推荐引用方式 GB/T 7714 | Dai ZH,Wang GR,Liu LQ,et al. Mechanical behavior and properties of hydrogen bonded graphene/polymer nano-interfaces[J]. COMPOSITES SCIENCE AND TECHNOLOGY,2016,136:1-9. |
APA | Dai ZH.,Wang GR.,Liu LQ.,Hou Y.,魏悦广.,...&Zhang, Z .(2016).Mechanical behavior and properties of hydrogen bonded graphene/polymer nano-interfaces.COMPOSITES SCIENCE AND TECHNOLOGY,136,1-9. |
MLA | Dai ZH,et al."Mechanical behavior and properties of hydrogen bonded graphene/polymer nano-interfaces".COMPOSITES SCIENCE AND TECHNOLOGY 136(2016):1-9. |
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