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Composition-based methane adsorption models for the Qiongzhusi Formation shale in Deyang-Anyue rift trough of Sichuan Basin, China, and its comparison with the Wufeng-Longmaxi Formation shale
Wu, Jianfa1; Jiang WB(江文滨)2,3; Luo, Chao1; Lin M(林缅)2,3; Zhong, Kesu1; He YF(何宜繁)1; Li, Yanyou1; Nie, Yuhan1; Ji LL(姬莉莉)2,3; Cao GH(曹高辉)2
Corresponding AuthorJiang, Wenbin(jiangwenbin@imech.ac.cn)
Source PublicationFUEL
2025-08-01
Volume393Pages:15
ISSN0016-2361
AbstractThe Lower Cambrian Qiongzhusi (QZS) Formation marine shale in the aulacogen-uplift overlap area of DeyangAnyue rift trough of Sichuan Basin, China, has emerged as a key target for the next stage of shale gas development. However, a lack of quantitative understanding of methane adsorption characteristics and their relationship with composition hinders accurate gas content evaluation and optimal target selection. In this study, over 80 samples from different sublayers of the QZS Formation in two wells located in the rift trough and the slope belt were comprehensively analyzed. Multivariate linear regression identified organic matter and clay minerals as the dominant factors controlling methane adsorption. Composition-based models were developed to quantify adsorption capacity by summing the products of unit-content adsorption capacities of organic matter and clay minerals and their respective contents. Through the significant correlation between adsorption capacity and micropore volume, the strong control of organic matter and clay minerals on micropore volume was revealed. Compared to the Wufeng-Longmaxi (WF-LMX) Formation shale, the QZS Formation shale exhibits lessdeveloped micropores in unit-content clay minerals, and the unit-clay-mineral methane adsorption capacities are lower for the two wells. However, the QZS shale shows a higher meso/macropore volume fraction in the same porosity range and stronger matrix flow capacity, which enhances rapid gas desorption. These findings provide critical insights into the pore structure and adsorption mechanisms of the QZS Formation, offering theoretical guidance for selecting favorable development areas and optimizing shale gas extraction strategies in the Sichuan Basin.
KeywordShale Gas Qiongzhusi Formation Wufeng-Longmaxi Formation Methane Adsorption Organic Matter Clay Mineral
DOI10.1016/j.fuel.2025.134976
Indexed BySCI ; EI
Language英语
WOS IDWOS:001442122600001
WOS KeywordSUPERCRITICAL METHANE ; SORPTION ISOTHERMS ; GAS-ADSORPTION ; BLACK SHALES ; EQUATION
WOS Research AreaEnergy & Fuels ; Engineering
WOS SubjectEnergy & Fuels ; Engineering, Chemical
Funding ProjectNational Natural Science Foundation of China[42030808] ; Project of Chinese Academy of Sciences[GJ04010303] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA14010304] ; Petro-China Science and Technology Major Project[2019F-31-01] ; Petro-China Science and Technology Major Project[2023ZZ21YJ04]
Funding OrganizationNational Natural Science Foundation of China ; Project of Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Petro-China Science and Technology Major Project
Classification一类
Ranking1
Contributor江文滨
Citation statistics
Document Type期刊论文
Identifierhttp://dspace.imech.ac.cn/handle/311007/100246
Collection流固耦合系统力学重点实验室
Affiliation1.PetroChina Southwest Oil & Gasfield Co, Shale Gas Res Inst, Chengdu 610051, Sichuan, Peoples R China;
2.Chinese Acad Sci, Inst Mech, Beijing 100190, Peoples R China;
3.Univ Chinese Acad Sci, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Wu, Jianfa,Jiang WB,Luo, Chao,et al. Composition-based methane adsorption models for the Qiongzhusi Formation shale in Deyang-Anyue rift trough of Sichuan Basin, China, and its comparison with the Wufeng-Longmaxi Formation shale[J]. FUEL,2025,393:15.
APA Wu, Jianfa.,江文滨.,Luo, Chao.,林缅.,Zhong, Kesu.,...&曹高辉.(2025).Composition-based methane adsorption models for the Qiongzhusi Formation shale in Deyang-Anyue rift trough of Sichuan Basin, China, and its comparison with the Wufeng-Longmaxi Formation shale.FUEL,393,15.
MLA Wu, Jianfa,et al."Composition-based methane adsorption models for the Qiongzhusi Formation shale in Deyang-Anyue rift trough of Sichuan Basin, China, and its comparison with the Wufeng-Longmaxi Formation shale".FUEL 393(2025):15.
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