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Adsorption of enantiomeric and racemic tyrosine on Cu(111): A scanning tunneling microscopy study | |
Wang D; Xu QM; Wan LJ; Bai CL; Jin G(靳刚); Wan, LJ (reprint author), Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China. | |
发表期刊 | Langmuir |
2003 | |
卷号 | 19期号:6页码:1958-1962 |
ISSN | 0743-7463 |
摘要 | The adsorption of enantiomers and a racemic mixture of tyrosine (tyr) on Cu(111) has been investigated by cyclic voltammetry and electrochemical scanning tunneling microscopy. D-tyr and L-tyr molecules adsorb on Cu(111) and show a (4 x 4) structure. The m; The adsorption of enantiomers and a racemic mixture of tyrosine (tyr) on Cu(111) has been investigated by cyclic voltammetry and electrochemical scanning tunneling microscopy. D-tyr and L-tyr molecules adsorb on Cu(111) and show a (4 x 4) structure. The mirror symmetry between two adlayers is demonstrated by high-resolution scanning tunneling microscope images. The spontaneous separation of racemate into homochiral domains is observed. The result presented here is hoped to supply direct evidence for the chiral adlayer ordering at the solid/liquid interface. |
学科领域 | 力学 |
DOI | 10.1021/la026821u |
收录类别 | SCI ; EI |
语种 | 英语 |
WOS记录号 | WOS:000181562700011 |
关键词[WOS] | CHIRAL METAL-SURFACES ; MOLECULAR CHIRALITY ; L-LYSINE ; MONOLAYERS ; ASSEMBLIES ; ELECTRODE ; CU(001) ; FILMS ; FTIR |
WOS研究方向 | Chemistry ; Materials Science |
WOS类目 | Chemistry, Multidisciplinary ; Chemistry, Physical ; Materials Science, Multidisciplinary |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://dspace.imech.ac.cn/handle/311007/15538 |
专题 | 力学所知识产出(1956-2008) |
通讯作者 | Wan, LJ (reprint author), Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China. |
推荐引用方式 GB/T 7714 | Wang D,Xu QM,Wan LJ,et al. Adsorption of enantiomeric and racemic tyrosine on Cu(111): A scanning tunneling microscopy study[J]. Langmuir,2003,19,6,:1958-1962. |
APA | Wang D,Xu QM,Wan LJ,Bai CL,靳刚,&Wan, LJ .(2003).Adsorption of enantiomeric and racemic tyrosine on Cu(111): A scanning tunneling microscopy study.Langmuir,19(6),1958-1962. |
MLA | Wang D,et al."Adsorption of enantiomeric and racemic tyrosine on Cu(111): A scanning tunneling microscopy study".Langmuir 19.6(2003):1958-1962. |
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