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Catalytic reduction of nitric oxide by carbon monoxide over coal gangue hollow ball
Li S(李森); Yu JL; Wei XL(魏小林); Guo XF; Chen Y; Li, S (reprint author), Chinese Acad Sci, Inst Mech, State Key Lab High Temp Gas Dynam, 15 Beisihuanxi Rd, Beijing 100190, Peoples R China.
发表期刊Fuel Processing Technology
2014-09
卷号125页码:163-169
ISSN0378-3820
摘要The catalytic effect of coal gangue hollow ball with open pores on NO reduction by CO in fluidized bed was investigated, and the kinetics for the catalytic reduction of NO using CO was evaluated. In the absence of water vapor at 773-923 K, the reaction rate constant was k = 5210 exp(-113600/(RT)). NO reduction ratio rapidly increased with reaction residence time at initial stage (<1 s) and T > 873 K; high NO reduction ratio was achieved by increasing reaction temperature when the initial concentration ratio of CO to NO was less than 4. In the presence of water, the catalytic effect of coal gangue hollow ball on NO reduction was weakened, and the reaction rate constant was k = 0.31 exp(-60750/(RT)). NO reduction ratio is less than 02 when reaction residence time was 2.5 s at T <= 923 K when the initial concentration ratio of CO to NO was 4, and the initial concentration ratio of CO to NO had negligible effect on NO reduction ratio at T <= 923 K. (C) 2014 Elsevier B.V. All rights reserved.
关键词Coal Gangue Hollow Ball No Reduction Kinetic Modeling Carbon Monoxide
学科领域Chemistry ; Energy & Fuels ; Engineering
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收录类别SCI ; EI
语种英语
WOS记录号WOS:000337876300020
项目资助者Financial support by National Natural Science Foundation of China (No. 51376189) is acknowledged.
课题组名称LHD高效洁净燃烧(CPCR)
论文分区二类
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被引频次:15[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://dspace.imech.ac.cn/handle/311007/49040
专题高温气体动力学国家重点实验室
通讯作者Li, S (reprint author), Chinese Acad Sci, Inst Mech, State Key Lab High Temp Gas Dynam, 15 Beisihuanxi Rd, Beijing 100190, Peoples R China.
推荐引用方式
GB/T 7714
Li S,Yu JL,Wei XL,et al. Catalytic reduction of nitric oxide by carbon monoxide over coal gangue hollow ball[J]. Fuel Processing Technology,2014,125:163-169.
APA Li S,Yu JL,Wei XL,Guo XF,Chen Y,&Li, S .(2014).Catalytic reduction of nitric oxide by carbon monoxide over coal gangue hollow ball.Fuel Processing Technology,125,163-169.
MLA Li S,et al."Catalytic reduction of nitric oxide by carbon monoxide over coal gangue hollow ball".Fuel Processing Technology 125(2014):163-169.
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