| Deformation of Surface Nanobubbles Induced by Substrate Hydrophobicity |
| Wei JC(韦佳辰); Zhang XR; Song F(宋凡) ; Song, F (reprint author), Chinese Acad Sci, Inst Mech, State Key Lab Nonlinear Mech, 15 Beisihuanxi Rd, Beijing 100190, Peoples R China.; Song, F (reprint author), Univ Chinese Acad Sci, Sch Engn Sci, Beijing 100049, Peoples R China.; Zhang, XR (reprint author), Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China.
|
| 发表期刊 | LANGMUIR
 |
| 2016
|
| 卷号 | 32期号:49页码:13003-13008 |
| ISSN | 0743-7463
|
| 摘要 | Recent experimental measurements have shown that there exists a population of nanobubbles with different curvature radii, whereas both computer simulations and theoretical analysis indicated that the curvature radii of different nanobubbles should be the same at a given supersaturation. To resolve such inconsistency, we perform molecular dynamics simulations on surface nanobubbles that are stabilized by heterogeneous substrates either in the geometrical heterogeneity model (GHM) or in the chemical heterogeneity model (CHM) and propose that the inconsistency could be ascribed to the substrate-induced nanobubble deformation. We find that, as expected from theory and computer simulation, for either the GHM or the CHM, there exists a universal upper limit of contact angle for the nanobubbles, which is determined by the degree of supersaturation alone. By analyzing the evolution of the shape of nanobubbles as a function of substrate hydrophobicity that is controlled here by the liquid-solid interaction, two different origins of nanobubble deformation are identified. For substrates in the GHM, where the contact line is pinned by surface roughness, variation in the liquid-solid interaction changes only the location of the contact line and the measured contact angle; without causing a change in the nanobubble curvature. For substrates in the CHM, however, the liquid-solid interaction exerted by the bottom substrate can deform the vapor-liquid interface, resulting in variations in both the curvature of the vapor-liquid interface and the contact angle. |
| DOI | 10.1021/acs.langmuir.6b03236
|
| URL | 查看原文
|
| 收录类别 | SCI
; EI
|
| 语种 | 英语
|
| WOS记录号 | WOS:000389866300006
|
| WOS研究方向 | Chemistry
; Materials Science
|
| WOS类目 | Chemistry, Multidisciplinary
; Chemistry, Physical
; Materials Science, Multidisciplinary
|
| 项目资助者 | National Natural Science Foundation of China [11602279, 21276007, 11232013, 11472285, 91434204]
|
| 课题组名称 | LNM生物材料微结构和力学性能
|
| 论文分区 | 一类
|
| 引用统计 |
|
| 文献类型 | 期刊论文
|
| 条目标识符 | http://dspace.imech.ac.cn/handle/311007/59980
|
| 专题 | 非线性力学国家重点实验室
|
| 通讯作者 | Song, F (reprint author), Chinese Acad Sci, Inst Mech, State Key Lab Nonlinear Mech, 15 Beisihuanxi Rd, Beijing 100190, Peoples R China.; Song, F (reprint author), Univ Chinese Acad Sci, Sch Engn Sci, Beijing 100049, Peoples R China.; Zhang, XR (reprint author), Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China. |
推荐引用方式
GB/T 7714 |
Wei JC,Zhang XR,Song F,et al. Deformation of Surface Nanobubbles Induced by Substrate Hydrophobicity[J]. LANGMUIR,2016,32,49,:13003-13008.
|
| APA |
韦佳辰,Zhang XR,宋凡,Song, F ,Song, F ,&Zhang, XR .(2016).Deformation of Surface Nanobubbles Induced by Substrate Hydrophobicity.LANGMUIR,32(49),13003-13008.
|
| MLA |
韦佳辰,et al."Deformation of Surface Nanobubbles Induced by Substrate Hydrophobicity".LANGMUIR 32.49(2016):13003-13008.
|
修改评论