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Effect of void structures crystalline structure on the shear moduli of charged colloidal crystals
Wang LW(王林伟); Xu SH(徐升华); Zhou HW(周宏伟); Sun ZW(孙址伟); Xu F; Wang, LW (reprint author), Beijing Jiaotong Univ, Sch Civil Engn, Beijing 100044, Peoples R China.; Wang, LW; Xu, SH (reprint author), Chinese Acad Sci, Inst Mech, Key Lab Micrograv, Beijing 100190, Peoples R China.; Xu, SH (reprint author), Univ Chinese Acad Sci, Sch Engn Sci, Beijing 100049, Peoples R China.
Source PublicationCOLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
2017
Volume516Pages:115-120
ISSN0927-7757
Abstract

Shear moduli of colloidal crystals with different nearest inter-particle distances. The results show the consistency between the results of our modified model and the experimental measurements by torsional resonance spectroscopy. [GRAPHICS] The existing theoretical model relating shear modulus to inter-particle interaction potential always significantly overestimates the modulus compared with its experimental value for colloidal crystal formed by highly-charged particles. We suppose that such huge disagreements between the theoretical and experimental results are due to that the theoretical model is derived from perfect crystalline structures. To modify the theoretical model, the effect of void defects is introduced to the model and the Sogami-Ise potential model is adopted instead of the commonly used Yukawa potential model. It is shown that with these two modifications the shear modulus model produces results much more consistent with the experimental ones. (C) 2016 Elsevier B.V. All rights reserved.

DOI10.1016/j.colsurfa.2016.11.060
URL查看原文
Indexed BySCI ; EI
Language英语
WOS IDWOS:000393727700013
WOS KeywordColloidal crystals ; Void defects ; Shear modulus ; Effective charge ; Modelling
WOS Research AreaChemistry
WOS SubjectChemistry, Physical
Funding OrganizationWe gratefully acknowledge financial support by grants 11302226, 11572322 and 11672295 from the National Natural Science Foundation of China.
DepartmentNML复杂流体
Classification二类
Ranking1
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://dspace.imech.ac.cn/handle/311007/60097
Collection微重力重点实验室
Corresponding AuthorWang, LW (reprint author), Beijing Jiaotong Univ, Sch Civil Engn, Beijing 100044, Peoples R China.; Wang, LW; Xu, SH (reprint author), Chinese Acad Sci, Inst Mech, Key Lab Micrograv, Beijing 100190, Peoples R China.; Xu, SH (reprint author), Univ Chinese Acad Sci, Sch Engn Sci, Beijing 100049, Peoples R China.
Recommended Citation
GB/T 7714
Wang LW,Xu SH,Zhou HW,et al. Effect of void structures crystalline structure on the shear moduli of charged colloidal crystals[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,2017,516:115-120.
APA 王林伟.,徐升华.,周宏伟.,孙址伟.,Xu F.,...&Xu, SH .(2017).Effect of void structures crystalline structure on the shear moduli of charged colloidal crystals.COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,516,115-120.
MLA 王林伟,et al."Effect of void structures crystalline structure on the shear moduli of charged colloidal crystals".COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 516(2017):115-120.
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