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Using electrochemistry-total internal reflection imaging ellipsometry to monitor biochemical oxygen demand with polyaniline modified electrode
Shen J(沈嘉)1,2; Liu W(刘巍)1; Niu Y(牛宇)1; Li M3; Jin G(靳刚)1
Corresponding AuthorNiu, Yu(niuyu@imech.ac.cn) ; Li, Meng(limeng@nju.edu.cn)
Source PublicationJOURNAL OF VACUUM SCIENCE & TECHNOLOGY B
2020-03-01
Volume38Issue:2Pages:7
ISSN2166-2746
AbstractBiochemical oxygen demand (BOD) is an important indicator for characterizing organic pollution in water. So various BOD sensors have been developed for BOD detection. BOD sensors based on a Clark electrode have the problem of signal drift. To overcome this problem, a combined electrochemical and total internal reflection imaging ellipsometry sensor has been proposed. To improve the sensitivity, polyaniline (PAn) and PAn incorporated with Fe(III) meso-tetra (4-sulfonatophenyl) porphyrin (FeTSPP) have been introduced on the working electrode. The results show that the combination system is effective for BOD detection with PAn. By incorporating FeTSPP, the optical and electrochemical responses of a PAn modified gold chip to BOD are improved significantly. Finally, the relationship between the optical and electrochemical signals is investigated by establishing a glass/Au/PAn-based film/liquid model. The analysis reveals that both signals represent the ratio change of the oxidized state of PAn in a similar way.
DOI10.1116/1.5129606
Indexed BySCI ; EI
Language英语
WOS IDWOS:000569100800005
WOS KeywordDISSOLVED-OXYGEN ; BIOSENSOR ; SENSOR ; FILM
WOS Research AreaEngineering ; Science & Technology - Other Topics ; Physics
WOS SubjectEngineering, Electrical & Electronic ; Nanoscience & Nanotechnology ; Physics, Applied
Funding ProjectYouth Innovation Promotion Association of the Chinese Academy of Sciences[2017026] ; National Natural Science Foundation of China (NNSFC)[81872584] ; National Basic Research Program of China[2015CB352100] ; International Science and Technology Cooperation Program of China[2015DFG32390]
Funding OrganizationYouth Innovation Promotion Association of the Chinese Academy of Sciences ; National Natural Science Foundation of China (NNSFC) ; National Basic Research Program of China ; International Science and Technology Cooperation Program of China
ClassificationQ3
Ranking1
ContributorNiu, Yu ; Li, Meng
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://dspace.imech.ac.cn/handle/311007/85223
Collection微重力重点实验室
Affiliation1.Chinese Acad Sci, Inst Mech, Beijing Key Lab Engn Construct & Mech, NML, 15 Bei Si Huan West, Beijing 100190, Peoples R China;
2.Univ Chinese Acad Sci, Sch Engn Sci, 19 Yu Quan Rd, Beijing 100049, Peoples R China;
3.Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Analyt Chem Life Sci, Nanjing 210093, Peoples R China
Recommended Citation
GB/T 7714
Shen J,Liu W,Niu Y,et al. Using electrochemistry-total internal reflection imaging ellipsometry to monitor biochemical oxygen demand with polyaniline modified electrode[J]. JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B,2020,38,2,:7.
APA 沈嘉,刘巍,牛宇,Li M,&靳刚.(2020).Using electrochemistry-total internal reflection imaging ellipsometry to monitor biochemical oxygen demand with polyaniline modified electrode.JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B,38(2),7.
MLA 沈嘉,et al."Using electrochemistry-total internal reflection imaging ellipsometry to monitor biochemical oxygen demand with polyaniline modified electrode".JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B 38.2(2020):7.
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