Experiments have been performed to explore the combustion behaviors of spherical micron-sized aluminum (μμAl) particles and liquid water for Al particle sizes in the range of 3.5–25  μm3.5–25  μm. The ignition of quasi-homogeneous μμAl/water mixtures was successfully implemented by employing a novel ignition method, and self-sustained flame propagation was obtained in the mixtures over a broad range of fuel-equivalence ratio ϕϕ. The burning rates, flammability limits, and thermal structure of the propagating flame were determined. The combustion products were also analyzed. For the particle sizes considered, the burning rates were found to first increase and then decrease as ϕϕ increased, with the maximum values occurring at ϕ=1.7–2.0ϕ=1.7–2.0 and substantially lower than nano-Al/H2OAl/H2O mixtures. The dependence of the burning rate on particle size follows a power law, rb∼D−0.18rb∼D−0.18, indicating that the reaction process of μAlμAl and water is kinetically controlled. Base on the experimental observations, a simplified flame propagation model was developed to provide insight into the effects of particle size and equivalence ratio. Combustion product analyses revealed that Al residues increased as ϕϕ was further increased from 0.7, and the combustion efficiency of aluminum decreased accordingly.