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The mechanical response and microscopic deformation mechanism of graphene foams tuned by long carbon nanotubes and short crosslinkers
Wang,Shuai1; Yang T(杨田)2,3; Wang C(王超)2,3; Liang,Lihong1
发表期刊PHYSICAL CHEMISTRY CHEMICAL PHYSICS
2022-11-28
页码11
ISSN1463-9076
摘要

The mechanical response of graphene foams (GrFs) can be enhanced by both short crosslinkers (e.g. C-C bond) and long carbon nanotubes (CNTs) in experiments; however, the underlying mechanism is still unclear. Here, a coarse-grained molecular dynamics method is used to study the mechanical response and microscopic mechanism of GrF interconnected by both short crosslinkers and long CNTs (named CNT bonded GrF, CbGrF) under tension and compression, and the effect of the properties of graphene and CNTs on the mechanical properties of CbGrF is also investigated. Compared with short bonds, long CNTs play a reinforcing role at a larger tensile strain, leading to larger tensile strength and toughness. Under compression, the sliding and rotation of graphene sheets in CbGrF are prevented by long CNTs, resulting in higher compressive stiffness than that of pure GrFs. Furthermore, the tensile and compressive moduli increase by more than 300% with increasing thickness of graphene sheets from 1 to 9 layers; they increase by no more than 50% as the CNT bending stiffness increases and are almost independent of the stretching stiffness of CNTs. These results should be helpful for understanding the tunability of GrFs using both short and long crosslinkers and guiding the preparation of advanced GrF-based composites.

DOI10.1039/d2cp04221e
收录类别SCI ; EI
语种英语
WOS记录号WOS:000894600100001
关键词[WOS]SUPER-ELASTICITY ; ENERGY-STORAGE ; AEROGELS ; OXIDE ; PERFORMANCE ; CONVERSION ; STRENGTH
WOS研究方向Chemistry ; Physics
WOS类目Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
资助项目National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Fundamental Research Funds for the Central Universities of China ; [12002034] ; [11972348] ; [12172035] ; [92160203] ; [XDB22040503] ; [buctrc201930]
项目资助者National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Fundamental Research Funds for the Central Universities of China
论文分区二类/Q1
力学所作者排名1
RpAuthorWang, Chao
引用统计
被引频次:7[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://dspace.imech.ac.cn/handle/311007/91199
专题非线性力学国家重点实验室
作者单位1.Beijing Univ Chem Technol, Coll Mech & Elect Engn, Beijing 100029, Peoples R China;
2.Chinese Acad Sci, Inst Mech, LNM, Beijing 100190, Peoples R China;
3.Univ Chinese Acad Sci, Sch Engn Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Wang,Shuai,Yang T,Wang C,et al. The mechanical response and microscopic deformation mechanism of graphene foams tuned by long carbon nanotubes and short crosslinkers[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2022:11.
APA Wang,Shuai,Yang T,Wang C,&Liang,Lihong.(2022).The mechanical response and microscopic deformation mechanism of graphene foams tuned by long carbon nanotubes and short crosslinkers.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,11.
MLA Wang,Shuai,et al."The mechanical response and microscopic deformation mechanism of graphene foams tuned by long carbon nanotubes and short crosslinkers".PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2022):11.
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