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The mechanical response and microscopic deformation mechanism of graphene foams tuned by long carbon nanotubes and short crosslinkers
Wang,Shuai1; Yang T(杨田)2,3; Wang C(王超)2,3; Liang,Lihong1
Source PublicationPHYSICAL CHEMISTRY CHEMICAL PHYSICS
2022-11-28
Pages11
ISSN1463-9076
Abstract

The mechanical response of graphene foams (GrFs) can be enhanced by both short crosslinkers (e.g. C-C bond) and long carbon nanotubes (CNTs) in experiments; however, the underlying mechanism is still unclear. Here, a coarse-grained molecular dynamics method is used to study the mechanical response and microscopic mechanism of GrF interconnected by both short crosslinkers and long CNTs (named CNT bonded GrF, CbGrF) under tension and compression, and the effect of the properties of graphene and CNTs on the mechanical properties of CbGrF is also investigated. Compared with short bonds, long CNTs play a reinforcing role at a larger tensile strain, leading to larger tensile strength and toughness. Under compression, the sliding and rotation of graphene sheets in CbGrF are prevented by long CNTs, resulting in higher compressive stiffness than that of pure GrFs. Furthermore, the tensile and compressive moduli increase by more than 300% with increasing thickness of graphene sheets from 1 to 9 layers; they increase by no more than 50% as the CNT bending stiffness increases and are almost independent of the stretching stiffness of CNTs. These results should be helpful for understanding the tunability of GrFs using both short and long crosslinkers and guiding the preparation of advanced GrF-based composites.

DOI10.1039/d2cp04221e
Indexed BySCI ; EI
Language英语
WOS IDWOS:000894600100001
WOS KeywordSUPER-ELASTICITY ; ENERGY-STORAGE ; AEROGELS ; OXIDE ; PERFORMANCE ; CONVERSION ; STRENGTH
WOS Research AreaChemistry ; Physics
WOS SubjectChemistry, Physical ; Physics, Atomic, Molecular & Chemical
Funding ProjectNational Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Fundamental Research Funds for the Central Universities of China ; [12002034] ; [11972348] ; [12172035] ; [92160203] ; [XDB22040503] ; [buctrc201930]
Funding OrganizationNational Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Fundamental Research Funds for the Central Universities of China
Classification二类/Q1
Ranking1
ContributorWang, Chao
Citation statistics
Cited Times:7[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://dspace.imech.ac.cn/handle/311007/91199
Collection非线性力学国家重点实验室
Affiliation1.Beijing Univ Chem Technol, Coll Mech & Elect Engn, Beijing 100029, Peoples R China;
2.Chinese Acad Sci, Inst Mech, LNM, Beijing 100190, Peoples R China;
3.Univ Chinese Acad Sci, Sch Engn Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Wang,Shuai,Yang T,Wang C,et al. The mechanical response and microscopic deformation mechanism of graphene foams tuned by long carbon nanotubes and short crosslinkers[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2022:11.
APA Wang,Shuai,Yang T,Wang C,&Liang,Lihong.(2022).The mechanical response and microscopic deformation mechanism of graphene foams tuned by long carbon nanotubes and short crosslinkers.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,11.
MLA Wang,Shuai,et al."The mechanical response and microscopic deformation mechanism of graphene foams tuned by long carbon nanotubes and short crosslinkers".PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2022):11.
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