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Mechanisms of the improved stiffness of flexible polymers under impact loading
Chen,Fengxiao1; Fan,Jitang1; Hui,David2; Wang C(王超)3; Yuan FP(袁福平)3; Wu XL(武晓雷)3
通讯作者Fan, Jitang(Jitang_fan@hotmail.com)
发表期刊NANOTECHNOLOGY REVIEWS
2022-12-16
卷号11期号:1页码:3281-3291
ISSN2191-9089
摘要The flexible polymers have an outstanding impact-resistant performance because of the improved stiffness upon a high speed loading. At the aspect of microstructure, the soft segments make an important contribution. In this article, molecular dynamics simulation is carried out to reveal the dynamic mechanical behavior of a mono helical soft segment. The tensile loadings at various strain rates are conducted. The stress-strain relations and strain rate dependencies of mechanical properties are derived. The evolution of potential energy with straining accompanied by the disentanglement of molecular chain is characterized. The characteristic molecular chain of dynamic mechanical response is determined. The intrinsic physical origins of straightening of characteristic molecular chain and bond angle expansion are explored. New parameters are defined to quantitatively analyze the micro mechanisms and their rate dependencies, which are linked to the dynamic mechanical properties. This work is full of interest to fill a knowledge gap of the physical origins of dynamic mechanical behavior of flexible polymers.
关键词soft segment flexible polymer stiffness strain rate molecular dynamics
DOI10.1515/ntrev-2022-0437
收录类别SCI ; EI
语种英语
WOS记录号WOS:000898094900001
关键词[WOS]SEGMENTED POLYURETHANES ; TEMPERATURE-DEPENDENCE ; AB-INITIO ; DEFORMATION ; COMPOSITES ; PROPERTY ; BEHAVIOR ; ALKANE ; MODEL
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS类目Chemistry, Multidisciplinary ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied
资助项目National Natural Science Foundation of China[11602024] ; 111 Project of China[G20012017001]
项目资助者National Natural Science Foundation of China ; 111 Project of China
论文分区二类/Q1
力学所作者排名3+
RpAuthorFan, Jitang
引用统计
被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://dspace.imech.ac.cn/handle/311007/91279
专题非线性力学国家重点实验室
作者单位1.Beijing Inst Technol, State Key Lab Explos Sci & Technol, Beijing, Peoples R China;
2.Univ New Orleans, Dept Mech Engn, Orleans, LA 70148 USA;
3.Chinese Acad Sci, Inst Mech, LNM, Beijing, Peoples R China
推荐引用方式
GB/T 7714
Chen,Fengxiao,Fan,Jitang,Hui,David,et al. Mechanisms of the improved stiffness of flexible polymers under impact loading[J]. NANOTECHNOLOGY REVIEWS,2022,11,1,:3281-3291.
APA Chen,Fengxiao,Fan,Jitang,Hui,David,王超,袁福平,&武晓雷.(2022).Mechanisms of the improved stiffness of flexible polymers under impact loading.NANOTECHNOLOGY REVIEWS,11(1),3281-3291.
MLA Chen,Fengxiao,et al."Mechanisms of the improved stiffness of flexible polymers under impact loading".NANOTECHNOLOGY REVIEWS 11.1(2022):3281-3291.
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