| Carbon Nanotube-Directed 7 GPa Heterocyclic Aramid Fiber and Its Application in Artificial Muscles | |
Yan, Dan1,2; Luo, Jiajun2,3; Wang, Shijun4; Han, Xiaocang1; Lei, Xudong5,6 ; Jiao, Kun1,2; Wu, Xianqian5,6; Qian, Liu1; Zhang, Xinshi2,3; Zhao, Xiaoxu1; Di, Jiangtao7; Zhang, Zhong4; Gao, Zhenfei2; Zhang, Jin1,2,3
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| 通讯作者 | Gao, Zhenfei(gaozf-cnc@pku.edu.cn) ; Zhang, Jin(jinzhang@pku.edu.cn) |
| 发表期刊 | ADVANCED MATERIALS
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| 2023-12-10 | |
| 页码 | 12 |
| ISSN | 0935-9648 |
| 摘要 | Poly(p-phenylene-benzimidazole-terephthalamide) (PBIA) fibers with excellent mechanical properties are widely used in fields that require impact-resistant materials such as ballistic protection and aerospace. The introduction of heterocycles in polymer chains increases their flexibility and makes it easier to optimize the fiber structure. However, the inadequate orientation of polymer chains is one of the main reasons for the large difference between the measured and theoretical mechanical properties of PBIA fibers. Herein, carbon nanotubes (CNTs) are selected as an orientation seed. Their structural features allow CNTs to orient during the spinning process, which can induce an orderly arrangement of polymers and improve the orientation of the fiber microstructure. To ensure the complete 1D topology of long CNTs (approximate to 10 mu m), PBIA is used as an efficient dispersant to overcome dispersion challenges. The p-CNT/PBIA fibers (10 mu m single-walled carbon nanotube 0.025 wt%) exhibit an increase of 22% in tensile strength and 23% in elongation, with a maximum tensile strength of 7.01 +/- 0.31 GPa and a reinforcement efficiency of 893.6. The artificial muscle fabricated using CNT/PBIA fibers exhibits a 34.8% contraction and a 25% lifting of a 2 kg dumbbell, providing a promising paradigm for high-performance organic fibers as high-load smart actuators. The damage-free single-walled carbon nanotubes (SWNTs) dispersed using poly(p-phenylene-benzimidazole-terephthalamide) (PBIA) are selected as the orientation seed to improve the fiber microstructure and the mechanical properties. The p-SWNT/PBIA fibers exhibit an increase of 22% in tensile strength and 23% in elongation, with a maximum tensile strength of 7.01 +/- 0.31 GPa and a reinforcement efficiency of 893.6.image |
| 关键词 | 1D topology artificial muscles carbon nanotubes damage-free dispersion heterocyclic aramid fibers mechanical properties orientation seed |
| DOI | 10.1002/adma.202306129 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:001118515200001 |
| 关键词[WOS] | NANOCOMPOSITE FIBERS ; COMPOSITE FIBERS ; HIGH-STRENGTH ; TENSILE PROPERTIES ; DISPERSION ; GRAPHENE ; FUNCTIONALIZATION ; KEVLAR |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| WOS类目 | Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter |
| 资助项目 | Ministry of Science and Technology of the People's Republic of China ; National Natural Science Foundation of China[52102035] ; Strategic Priority Research Program of CAS[XDB36030100] ; Beijing National Laboratory for Molecular Sciences[BNLMS-CXTD-202001] ; Chinese Academy of Sciences ; [2016YFA0200100] ; [2018YFA0703502] |
| 项目资助者 | Ministry of Science and Technology of the People's Republic of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of CAS ; Beijing National Laboratory for Molecular Sciences ; Chinese Academy of Sciences |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://dspace.imech.ac.cn/handle/311007/93638 |
| 专题 | 流固耦合系统力学重点实验室 |
| 通讯作者 | Gao, Zhenfei; Zhang, Jin |
| 作者单位 | 1.Peking Univ, Sch Mat Sci & Engn, Beijing 100871, Peoples R China 2.Beijing Graphene Inst BGI, Beijing 100095, Peoples R China 3.Peking Univ, Acad Adv Interdisciplinary Studies, Ctr Nano Chem, Beijing Natl Lab Mol Sci,Coll Chem & Mol Engn, Beijing 100871, Peoples R China 4.Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China 5.Chinese Acad Sci, Inst Mech, Beijing 100190, Peoples R China 6.Univ Chinese Acad Sci, Sch Engn Sci, Beijing 100049, Peoples R China 7.Chinese Acad Sci, Suzhou Inst Nanotech & Nanob, Adv Mat Div, Key Lab Multifunct Nanomat & Smart Syst, Suzhou 215123, Peoples R China 8.Tabriz Univ, Fac Chem & Petr Engn, Email, Iran |
| 推荐引用方式 GB/T 7714 | Yan, Dan,Luo, Jiajun,Wang, Shijun,et al. Carbon Nanotube-Directed 7 GPa Heterocyclic Aramid Fiber and Its Application in Artificial Muscles[J]. ADVANCED MATERIALS,2023:12. |
| APA | Yan, Dan.,Luo, Jiajun.,Wang, Shijun.,Han, Xiaocang.,Lei, Xudong.,...&Zhang, Jin.(2023).Carbon Nanotube-Directed 7 GPa Heterocyclic Aramid Fiber and Its Application in Artificial Muscles.ADVANCED MATERIALS,12. |
| MLA | Yan, Dan,et al."Carbon Nanotube-Directed 7 GPa Heterocyclic Aramid Fiber and Its Application in Artificial Muscles".ADVANCED MATERIALS (2023):12. |
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