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Tailoring nanoprecipitates to achieve ultrahigh strength (CoCrNi)94.5W3Ta2.5 medium-entropy alloys
Chen, Jin-Xi; Li, Tong; Tan, Yuan-Yuan1; Chen, Yan1; Wang, Hai-Ying1; Dai, Lan-Hong1,2,3
通讯作者Chen, Yan(chenyan@lnm.imech.ac.cn) ; Dai, Lan-Hong(lhdai@lnm.imech.ac.cn)
发表期刊MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
2024-02-01
卷号892页码:13
ISSN0921-5093
摘要Metallic materials with high mechanical performance are in constant demand by various engineering applications. However, most conventional strengthening mechanisms inevitably suffer from fiercely sacrificing ductility, which severely limits service safety of metallic alloys, especially under various harsh circumstances. In this work, a novel ultra-strong (CoCrNi)94.5W3Ta2.5 medium entropy alloy (MEA) with dual nanoprecipitates is successfully developed. By conducting multiple thermomechanical processes, not only quantities of coherent gamma" nanoprecipitates with D022 superlattice are introduced, but also massive semi-coherent eta nanoprecipitates with hexagonal D024 superlattice are reconstructed with appropriate sizes and distributions, meanwhile ultrafine grains are achieved, together enabling superior strength-ductility synergies. This MEA exhibits not only high tensile strength of about 1.7 GPa and ultimate elongation of 23.8 % at room temperature, but also ultra-high tensile strength of about 2.2 GPa and still sufficient ultimate elongation of 13.2 % at cryogenic temperature. In-depth microstructure characterization indicates that the nanoprecipitates are effective barriers to dislocation motion at the early stages of plastic deformation. Intriguingly, the slip and deformation twinning could be transmitted across the phase boundaries with increasing applied strain, ensuring both strength enhancement and plasticity maintenance. At cryogenic temperature, much more complex deformation mechanisms are activated, e. g., multiple slip systems and high-density deformation twins, facilitating even better mechanical properties. The design concept of strengthening materials via tailoring dual coherent nanoprecipitates may afford a paradigm to develop advanced metallic materials with ultrahigh strength.
关键词Dual nanoprecipitates Medium-entropy alloys Mechanical properties Precipitation hardening
DOI10.1016/j.msea.2023.146046
收录类别SCI
语种英语
WOS记录号WOS:001164657600001
关键词[WOS]MECHANICAL-PROPERTIES ; TENSILE PROPERTIES ; PRECIPITATION ; DUCTILITY ; COHERENT ; DEFORMATION ; BEHAVIOR ; MICROSTRUCTURE ; PLASTICITY ; AMBIENT
WOS研究方向Science & Technology - Other Topics ; Materials Science ; Metallurgy & Metallurgical Engineering
WOS类目Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
资助项目NSFC[U2141204] ; NSFC[11790292] ; NSFC[11972346] ; NSFC[12102433] ; NSFC Basic Science Center Program for ''Multi-scale Problems in Nonlinear Mechanics ''[11988102] ; Key Research Program of the Chinese Academy of Sciences ; National Key Research and Development Program of China[KFJJ21-01] ; Opening project of State Key Laboratory of Explosion Science and Technology[KFJJ18-14 M] ; Opening project of State Key Laboratory of Explosion Science and Technology[ZDRW -CN -2021-2-3] ; [2022YFC3320504-02]
项目资助者NSFC ; NSFC Basic Science Center Program for ''Multi-scale Problems in Nonlinear Mechanics '' ; Key Research Program of the Chinese Academy of Sciences ; National Key Research and Development Program of China ; Opening project of State Key Laboratory of Explosion Science and Technology
引用统计
文献类型期刊论文
条目标识符http://dspace.imech.ac.cn/handle/311007/94452
专题非线性力学国家重点实验室
通讯作者Chen, Yan; Dai, Lan-Hong
作者单位1.Chinese Acad Sci, Inst Mech, State Key Lab Nonlinear Mech, Beijing 100190, Peoples R China
2.State Key Lab Explos Sci & Technol, Beijing 100081, Peoples R China
3.Univ Chinese Acad Sci, Sch Engn Sci, Beijing 101408, Peoples R China
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GB/T 7714
Chen, Jin-Xi,Li, Tong,Tan, Yuan-Yuan,et al. Tailoring nanoprecipitates to achieve ultrahigh strength (CoCrNi)94.5W3Ta2.5 medium-entropy alloys[J]. MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING,2024,892:13.
APA Chen, Jin-Xi,Li, Tong,Tan, Yuan-Yuan,Chen, Yan,Wang, Hai-Ying,&Dai, Lan-Hong.(2024).Tailoring nanoprecipitates to achieve ultrahigh strength (CoCrNi)94.5W3Ta2.5 medium-entropy alloys.MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING,892,13.
MLA Chen, Jin-Xi,et al."Tailoring nanoprecipitates to achieve ultrahigh strength (CoCrNi)94.5W3Ta2.5 medium-entropy alloys".MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING 892(2024):13.
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