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| The interaction between poly(vinylpyrrolidone) and reversed micelles of water/AOT/n-heptane | |
Luan YX; Xu GY ; Dai GL(戴国亮); Sun ZW(孙祉伟); Hu L(胡良); Xu, GY (reprint author), Shandong Univ, Key Lab Colloid & Interface Chem Educ Minist, Jinan 250100, Peoples R China.
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| Source Publication | Colloid and Polymer Science
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| 2003 | |
| Volume | 282Issue:2Pages:110-118 |
| ISSN | 0303-402X |
| Abstract | The interactions between poly(vinylpyrrolidone) (PVP) and the reversed micelles composed of water, AOT, and n-heptane are investigated with the aid of phase diagram, measurements of conductivity and viscosity, Fourier transform infrared (FTIR) spectrum, and dynamic light scattering (DLS). The phase diagrams of water/AOT/heptane in the presence of and absence of PVP are given. The conductivity of the water/AOT/heptane reversed micelle without PVP initially increases and then decreases with the increase of water content, ω0 (the molar ratio of water to AOT), while the plots of conductivity (K) versus ω0 of the reversed micelle in the presence of PVP depend on the PVP concentrations. The plot of K versus ω0 with 2.0%wt PVP is similar to that without PVP. Only the ω0,max (the water content that the maximum conductivity corresponds to) is larger than that without PVP. Nevertheless, the conductivity of the reversed micelle containing more than 4%wt PVP always rises with the increase of the water content in the measured range. The DLS results indicate that the hydrodynamic radius (Rh) in the presence and absence of PVP rises with the increase of ω0. The plots with PVP and without PVP have almost the same value when ω0<17; and after that, it quickly increases with the increase of ω0. It is interesting to find that there is almost no effect of the PVP concentration on the viscosity and Rh of the reversed micelle at ω0 = 15. The FTIR results suggest that the contents of SO3--bound water and Na+-bound water both decrease with PVP added, while the content of the bulky-like water increases. However, the trapped water in the hydrophobic chain of the surfactant is nearly unaffected by PVP. It is also found from the FTIR that the carbonyl group stretching vibration of AOT is fitted into two sub-peaks, which center at 1740 and 1729 cm-1, corresponding to the trans and cis conformations of AOT, respectively. |
| Subject Area | 力学 |
| DOI | 10.1007/s00396-003-0900-7 |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000187126200002 |
| WOS Keyword | IN-OIL MICROEMULSIONS ; SODIUM BIS(2-ETHYLHEXYL) SULFOSUCCINATE ; FT-IR SPECTROSCOPY ; AEROSOL-OT ; SOLUBILIZED WATER ; LIGHT-SCATTERING ; N-HEPTANE ; INFRARED-SPECTROSCOPY ; POLY(ETHYLENE OXIDE) ; PERCOLATION PROCESS |
| WOS Research Area | Chemistry |
| WOS Subject | Chemistry, Physical ; Polymer Science |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://dspace.imech.ac.cn/handle/311007/17446 |
| Collection | 力学所知识产出(1956-2008) |
| Corresponding Author | Xu, GY (reprint author), Shandong Univ, Key Lab Colloid & Interface Chem Educ Minist, Jinan 250100, Peoples R China. |
| Recommended Citation GB/T 7714 | Luan YX,Xu GY,Dai GL,et al. The interaction between poly(vinylpyrrolidone) and reversed micelles of water/AOT/n-heptane[J]. Colloid and Polymer Science,2003,282,2,:110-118. |
| APA | Luan YX,Xu GY,戴国亮,孙祉伟,胡良,&Xu, GY .(2003).The interaction between poly(vinylpyrrolidone) and reversed micelles of water/AOT/n-heptane.Colloid and Polymer Science,282(2),110-118. |
| MLA | Luan YX,et al."The interaction between poly(vinylpyrrolidone) and reversed micelles of water/AOT/n-heptane".Colloid and Polymer Science 282.2(2003):110-118. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| FTIR.pdf（371KB） | 开放获取 | -- | View Application Full Text | |||
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