Kelvin方程的一种理论推导 | |
Alternative Title | Derivation of the Kelvin Equation |
闫红; 王小松; 朱如曾 | |
Source Publication | 物理化学学报=Acta Physico-Chimica Sinica |
2009 | |
Volume | 25Pages:640-644 |
ISSN | 1000-6818 |
Abstract | 从液滴平衡条件推导出严格意义的Kelvin方程,验证了其在宏观尺度可以转化为经典形式.利用Tolman方程,在考虑表面张力与曲率半径关系的条件下,给出在液体压缩性可忽略时,饱和蒸气压、蒸气密度、蒸气摩尔体积和曲率半径等关系;液体压缩性不可忽略时,得出以等温压缩系数和Tolman长度表示的饱和蒸气压与液滴半径的关系. |
Keyword | Kelvin方程 Tolman方程 表而张力 饱和蒸气压 曲率半径 |
DOI | 10.3866/PKU.WHXB20090422 |
Indexed By | SCI ; CSCD |
Language | 中文 |
WOS ID | WOS:000265197400008 |
WOS Keyword | MOLECULAR-DYNAMICS ; SURFACE-TENSION ; SPHERICAL INTERFACE ; PRESSURE ; SIMULATION |
WOS Research Area | Chemistry |
WOS Subject | Chemistry, Physical |
CSCD ID | CSCD:3611748 |
Citation statistics |
Cited Times:2[CSCD]
[CSCD Record]
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Document Type | 期刊论文 |
Identifier | http://dspace.imech.ac.cn/handle/311007/26598 |
Collection | 非线性力学国家重点实验室 |
Corresponding Author | 闫红 |
Recommended Citation GB/T 7714 | 闫红,王小松,朱如曾. Kelvin方程的一种理论推导[J]. 物理化学学报=Acta Physico-Chimica Sinica,2009,25:640-644. |
APA | 闫红,王小松,&朱如曾.(2009).Kelvin方程的一种理论推导.物理化学学报=Acta Physico-Chimica Sinica,25,640-644. |
MLA | 闫红,et al."Kelvin方程的一种理论推导".物理化学学报=Acta Physico-Chimica Sinica 25(2009):640-644. |
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