| Synthesis and hydrogen-storage performance of interpenetrated MOF-5/MWCNTs hybrid composite with high mesoporosity |
| Jiang H(姜恒) ; Feng YF(冯亚菲); Chen M(陈猛); Wang YR(王育人); Wang, YR (reprint author), Chinese Acad Sci, Inst Mech, Key Lab Micrograv Sci, Beijing 100190, Peoples R China.
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| 发表期刊 | International Journal of Hydrogen Energy
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| 2013-08-21
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| 卷号 | 38期号:25页码:10950-10955 |
| ISSN | 0360-3199
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| 摘要 | Metal-organic frameworks (MOFs) exhibiting high surface area and tunable pore size own broad application prospects. Compared with existing MOFs, MOF-5 [Zn4O(bdc)3] is a promising hydrogen storage material due to high H2 uptake capacity and thermostability. However, further wider applications of MOF-5 have been limited because atmospheric moisture levels cause MOF-5 instability. MOF-5 and multi-walled carbon nanotubes (MWCNTs) hybrid composite (denoted MOFMC) can enhance stability toward ambient moisture and improve hydrogen storage capacity. In this paper, the MOFMC, which has an interpenetrated structure with high mesoporosity, was synthesized. The MOFMC is denoted as Int-MOFMC-meso. It stored 2.02 wt% H2 at 77 K under 1 bar, which is higher than the MOF-5 with similar structure and the earlier reported MOFMC material. Moreover, the Int-MOFMC-meso can also show more excellent performance of thermostability and moisture stability than the MOF-5 with similar structure. |
| 关键词 | Metal-organic Frameworks
Interpenetrated Structure
Hydrogen-storage
Multi-walled Carbon Nanotubes
High Mesoporosity
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| 学科领域 | 新型材料的力学问题
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| DOI | 10.1016/j.ijhydene.2013.03.044
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| URL | 查看原文
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| 收录类别 | SCI
; EI
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| 语种 | 英语
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| WOS记录号 | WOS:000324563100096
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| 关键词[WOS] | METAL-ORGANIC FRAMEWORKS
; NANOPOROUS MATERIALS
; SORPTION PROPERTIES
; ADSORPTION
; CARBON
; MOF-5
; INCLUSION
; BEHAVIORS
; DESIGN
; SIZE
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| WOS研究方向 | Chemistry
; Electrochemistry
; Energy & Fuels
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| WOS类目 | Chemistry, Physical
; Electrochemistry
; Energy & Fuels
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| 项目资助者 | The authors wish to acknowledge the support from the National Natural Science Foundation of China (Nos. 11202211 and 11272315).
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| 课题组名称 | 中科院国家微重力实验室
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| 引用统计 |
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| 文献类型 | 期刊论文
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| 条目标识符 | http://dspace.imech.ac.cn/handle/311007/47434
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| 专题 | 微重力重点实验室
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| 通讯作者 | Wang, YR (reprint author), Chinese Acad Sci, Inst Mech, Key Lab Micrograv Sci, Beijing 100190, Peoples R China. |
推荐引用方式
GB/T 7714 |
Jiang H,Feng YF,Chen M,et al. Synthesis and hydrogen-storage performance of interpenetrated MOF-5/MWCNTs hybrid composite with high mesoporosity[J]. International Journal of Hydrogen Energy,2013,38,25,:10950-10955.
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| APA |
姜恒,冯亚菲,陈猛,王育人,&Wang, YR .(2013).Synthesis and hydrogen-storage performance of interpenetrated MOF-5/MWCNTs hybrid composite with high mesoporosity.International Journal of Hydrogen Energy,38(25),10950-10955.
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| MLA |
姜恒,et al."Synthesis and hydrogen-storage performance of interpenetrated MOF-5/MWCNTs hybrid composite with high mesoporosity".International Journal of Hydrogen Energy 38.25(2013):10950-10955.
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