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LASER-INDUCED FLUORESCENCE DETECTION OF COPPER ION WITH A RHODAMINE DERIVATIVE BY A CAPILLARY ELECTROPHORESIS MICROCHIP
Yu Y(于泳); Yang M; Shen F; Yu, Y (reprint author), Chinese Acad Sci, Natl Micrograv Lab, Inst Mech, Beijing 100190, Peoples R China.
会议录名称ICNMM 2009, PTS A-B
2009
会议名称7th International Conference on Nanochannels, Microchannels and Minichannels
会议日期JUN 22-24, 2009
会议地点Pohang, SOUTH KOREA
摘要A capillary electrophoresis microchip system with a confocal LIF detector was successfully constructed. RBPhOH, a new fluorescence dye synthesized from rhodamine B, was first investigated in a glass microchip for the selective and sensitive determination of copper ion by LIP method. The influences of the pH value, concentration of running buffer, detection voltage, and sample loading time on the response of LIP detector were studied. RBPhOH dissolved in 20 mM pH 6.0 Tris containing 10% acetonitrile could detect copper ions with a detection limit of 1.34x10-7 mol L(-1) (S/N=3), an order of magnitude lower than those of conductivity detectors.
WOS记录号WOS:000286415600088
ISBN号978-0-7918-4349-9
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收录类别CPCI-S ; EI
语种英语
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文献类型会议论文
条目标识符http://dspace.imech.ac.cn/handle/311007/58881
专题微重力重点实验室
通讯作者Yu, Y (reprint author), Chinese Acad Sci, Natl Micrograv Lab, Inst Mech, Beijing 100190, Peoples R China.
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Yu Y,Yang M,Shen F,et al. LASER-INDUCED FLUORESCENCE DETECTION OF COPPER ION WITH A RHODAMINE DERIVATIVE BY A CAPILLARY ELECTROPHORESIS MICROCHIP[C]ICNMM 2009, PTS A-B,2009.
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