| Fabricating strong and tough aramid fibers by small addition of carbon nanotubes | |
Luo, Jiajun; Wen, Yeye; Jia, Xiangzheng; Lei XD(雷旭东) ; Gao, Zhenfei; Jian, Muqiang; Xiao, Zhihua; Li, Lanying; Zhang, Jiangwei; Li, Tao; Dong, Hongliang; Wu XQ(吴先前); Gao, Enlai; Jiao, Kun; Zhang, Jin
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| Source Publication | NATURE COMMUNICATIONS
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| 2023-05-25 | |
| Volume | 14Issue:1Pages:3019 |
| ISSN | 2041-1723 |
| Abstract | High-performance fibers are promising materials in the impact protection field but fabricating fibers with high strength and high toughness is challenging. Here, the authors polymerize carbon nanotubes into aramid fibers to simultaneously improve strength and toughness. Synthetic high-performance fibers present excellent mechanical properties and promising applications in the impact protection field. However, fabricating fibers with high strength and high toughness is challenging due to their intrinsic conflicts. Herein, we report a simultaneous improvement in strength, toughness, and modulus of heterocyclic aramid fibers by 26%, 66%, and 13%, respectively, via polymerizing a small amount (0.05 wt%) of short aminated single-walled carbon nanotubes (SWNTs), achieving a tensile strength of 6.44 +/- 0.11 GPa, a toughness of 184.0 +/- 11.4 MJ m(-3), and a Young's modulus of 141.7 +/- 4.0 GPa. Mechanism analyses reveal that short aminated SWNTs improve the crystallinity and orientation degree by affecting the structures of heterocyclic aramid chains around SWNTs, and in situ polymerization increases the interfacial interaction therein to promote stress transfer and suppress strain localization. These two effects account for the simultaneous improvement in strength and toughness. |
| DOI | 10.1038/s41467-023-38701-4 |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:001001080600013 |
| WOS Research Area | Multidisciplinary Sciences |
| Funding Organization | Beijing Municipal Science and Technology Commission [2018YFA0703502] ; National Natural Science Foundation of China [52021006, 51720105003, 21790052, 52102035, 12272391, 12232020] ; Strategic Priority Research Program of CAS [XDB36030100] ; Beijing National Laboratory for Molecular Sciences [BNLMS-CXTD-202001] |
| Classification | 一类 |
| Ranking | 1 |
| Contributor | Jiao, K，Zhang, J，Jiao, K，Zhang, J，Gao, EL，Wu, XQ，Wu, XQ |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://dspace.imech.ac.cn/handle/311007/92385 |
| Collection | 流固耦合系统力学重点实验室 |
| Affiliation | 1.{Luo Jiajun, Wen Yeye, Xiao Zhihua, Jiao Kun, Zhang Jin} Peking Univ Acad Adv Interdisciplinary Studies Beijing Sci & Engn Ctr Nanocarbons Beijing Natl Lab Mol SciSch Mat Sci & EngnColl C Beijing 100871 Peoples R China 2.{Luo Jiajun, Wen Yeye, Gao Zhenfei, Jian Muqiang, Xiao Zhihua, Li Tao, Jiao Kun, Zhang Jin} Beijing Graphene Inst BGI Beijing 100095 Peoples R China 3.{Jia Xiangzheng, Gao Enlai} Wuhan Univ Sch Civil Engn Dept Engn Mech Wuhan 430072 Peoples R China 4.{Lei Xudong, Wu Xianqian} Chinese Acad Sci Inst Mech Beijing 100190 Peoples R China 5.{Lei Xudong, Wu Xianqian} Univ Chinese Acad Sci Sch Engn Sci Beijing 100049 Peoples R China 6.{Li Lanying} China Bluestar Chengrand Chem Co Ltd Chengdu 611430 Peoples R China 7.{Zhang Jiangwei} Inner Mongolia Univ Coll Chem & Chem Engn Sci Ctr Energy Mat & Chem Hohhot 010021 Peoples R China 8.{Dong Hongliang} Ctr High Pressure Sci & Technol Adv Res Shanghai 201203 Peoples R China |
| Recommended Citation GB/T 7714 | Luo, Jiajun,Wen, Yeye,Jia, Xiangzheng,et al. Fabricating strong and tough aramid fibers by small addition of carbon nanotubes[J]. NATURE COMMUNICATIONS,2023,14,1,:3019. |
| APA | Luo, Jiajun.,Wen, Yeye.,Jia, Xiangzheng.,雷旭东.,Gao, Zhenfei.,...&Zhang, Jin.(2023).Fabricating strong and tough aramid fibers by small addition of carbon nanotubes.NATURE COMMUNICATIONS,14(1),3019. |
| MLA | Luo, Jiajun,et al."Fabricating strong and tough aramid fibers by small addition of carbon nanotubes".NATURE COMMUNICATIONS 14.1(2023):3019. |
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| Jp2023A057.pdf（2897KB） | 期刊论文 | 出版稿 | 开放获取 | CC BY-NC-SA | View Download | |
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