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Modeling on ammonothermal growth of GaN semiconductor crystals
Chen QS(陈启生); Yan JY(颜君毅); Jiang YN(姜燕妮); Li W(李炜); Chen, QS; Chinese Acad Sci, Inst Mech, 15 Bei Si Huan Xi Rd, Beijing 100190, Peoples R China.
2012-06-15
发表期刊PROGRESS IN CRYSTAL GROWTH AND CHARACTERIZATION OF MATERIALS
卷号58期号:2-3页码:61-73
ISSN0960-8974
摘要Ammonothermal systems are modeled using fluid dynamics and heat and mass transfer models. The nutrient is considered as a porous media bed and the flow is simulated using the Darcy-Brinkman-Forchheimer model. The resulting governing equations are solved using the finite volume method. The effects of baffle design on flow pattern, heat and mass transfer in an autoclave are analyzed. For the research-grade autoclave with an internal diameter of 2.22 cm, the constraint for the GaN growth is found to be the growth kinetics and the total area of seed surfaces in the case of baffle opening of 10% (including the central opening of 5% and ring opening of 5%). The fluid flow across the baffle is a clockwise circulating flow which goes upwards in the central hole and downwards in the ring gap. Transport phenomena have been also studied in large-size ammonothermal growth systems with internal diameters of 4.44 cm and 10 cm. The flow pattern across the baffle changes to an anticlockwise circulating flow which goes upwards in the ring gap and downwards in the central hole in the case of 10% baffle opening. Since ammonothermal growth experiments are expensive and time-consuming, modeling becomes an effective tool for research and optimization of the ammonothermal growth processes.
关键词Gan Crystal Baffle Opening Ammonothermal Growth Mass Transfer Gallium Nitride Supercritical Ammonia Single-crystals Transport Seed
学科领域流体力学
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收录类别SCI ; EI
语种英语
WOS记录号WOS:000306029000001
项目资助者The project supported by the National Science Foundation of China (10972226, 50776098).
课题组名称NML流动稳定性与复杂流动
论文分区Q3
引用统计
被引频次:5[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://dspace.imech.ac.cn/handle/311007/46592
专题国家微重力实验室
通讯作者Chen, QS; Chinese Acad Sci, Inst Mech, 15 Bei Si Huan Xi Rd, Beijing 100190, Peoples R China.
推荐引用方式
GB/T 7714
Chen QS,Yan JY,Jiang YN,et al. Modeling on ammonothermal growth of GaN semiconductor crystals[J]. PROGRESS IN CRYSTAL GROWTH AND CHARACTERIZATION OF MATERIALS,2012,58(2-3):61-73.
APA 陈启生,颜君毅,姜燕妮,李炜,Chen, QS,&Chinese Acad Sci, Inst Mech, 15 Bei Si Huan Xi Rd, Beijing 100190, Peoples R China..(2012).Modeling on ammonothermal growth of GaN semiconductor crystals.PROGRESS IN CRYSTAL GROWTH AND CHARACTERIZATION OF MATERIALS,58(2-3),61-73.
MLA 陈启生,et al."Modeling on ammonothermal growth of GaN semiconductor crystals".PROGRESS IN CRYSTAL GROWTH AND CHARACTERIZATION OF MATERIALS 58.2-3(2012):61-73.
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